Excited-state properties of ruthenium(II) polypyridyl complexes containing asymmetric triazole ligands

Stefano Fanni; Tia E. Keyes; Christine M. O'Connor; Helen Hughes; Renyi Wang; Johannes G. Vos

doi:10.1016/S0010-8545(00)00245-9

Excited-state properties of ruthenium(II) polypyridyl complexes containing asymmetric triazole ligands

Stefano Fanni, Tia E. Keyes, Christine M. O'Connor, Helen Hughes, Renyi Wang, Johannes G. Vos

Research output: Contribution to journal › Review article › peer-review

64 Citations (Scopus)

Abstract

The photochemical and photophysical properties of ruthenium polypyridyl complexes containing 1,24-triazole-based ligands, such as pyridine- and pyrazine triazoles are reviewed. The excited-state behaviour of such complexes is discussed in relation to the asymmetry inherently present in these ligands. For the pyridine triazole-containing complexes a series of photochemically induced isomerisations is reported. Pyrazine triazole compounds show a very unusual dual emission, which has been investigated using temperature dependent emission lifetime studies and partial deuteriation.

Original language	English
Pages (from-to)	77-86
Number of pages	10
Journal	Coordination Chemistry Reviews
Volume	208
Issue number	1
DOIs	https://doi.org/10.1016/S0010-8545(00)00245-9
Publication status	Published - 2000

Keywords

Excited states
Photochemistry
Ruthenium
Triazole

Access to Document

10.1016/S0010-8545(00)00245-9

Cite this

@article{cc888e7c8d74404a94dc8731c328f055,

title = "Excited-state properties of ruthenium(II) polypyridyl complexes containing asymmetric triazole ligands",

abstract = "The photochemical and photophysical properties of ruthenium polypyridyl complexes containing 1,24-triazole-based ligands, such as pyridine- and pyrazine triazoles are reviewed. The excited-state behaviour of such complexes is discussed in relation to the asymmetry inherently present in these ligands. For the pyridine triazole-containing complexes a series of photochemically induced isomerisations is reported. Pyrazine triazole compounds show a very unusual dual emission, which has been investigated using temperature dependent emission lifetime studies and partial deuteriation.",

keywords = "Excited states, Photochemistry, Ruthenium, Triazole",

author = "Stefano Fanni and Keyes, {Tia E.} and O'Connor, {Christine M.} and Helen Hughes and Renyi Wang and Vos, {Johannes G.}",

year = "2000",

doi = "10.1016/S0010-8545(00)00245-9",

language = "English",

volume = "208",

pages = "77--86",

journal = "Coordination Chemistry Reviews",

issn = "0010-8545",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Excited-state properties of ruthenium(II) polypyridyl complexes containing asymmetric triazole ligands

AU - Fanni, Stefano

AU - Keyes, Tia E.

AU - O'Connor, Christine M.

AU - Hughes, Helen

AU - Wang, Renyi

AU - Vos, Johannes G.

PY - 2000

Y1 - 2000

N2 - The photochemical and photophysical properties of ruthenium polypyridyl complexes containing 1,24-triazole-based ligands, such as pyridine- and pyrazine triazoles are reviewed. The excited-state behaviour of such complexes is discussed in relation to the asymmetry inherently present in these ligands. For the pyridine triazole-containing complexes a series of photochemically induced isomerisations is reported. Pyrazine triazole compounds show a very unusual dual emission, which has been investigated using temperature dependent emission lifetime studies and partial deuteriation.

AB - The photochemical and photophysical properties of ruthenium polypyridyl complexes containing 1,24-triazole-based ligands, such as pyridine- and pyrazine triazoles are reviewed. The excited-state behaviour of such complexes is discussed in relation to the asymmetry inherently present in these ligands. For the pyridine triazole-containing complexes a series of photochemically induced isomerisations is reported. Pyrazine triazole compounds show a very unusual dual emission, which has been investigated using temperature dependent emission lifetime studies and partial deuteriation.

KW - Excited states

KW - Photochemistry

KW - Ruthenium

KW - Triazole

UR - http://www.scopus.com/inward/record.url?scp=0033820592&partnerID=8YFLogxK

U2 - 10.1016/S0010-8545(00)00245-9

DO - 10.1016/S0010-8545(00)00245-9

M3 - Review article

AN - SCOPUS:0033820592

SN - 0010-8545

VL - 208

SP - 77

EP - 86

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

IS - 1

ER -

Excited-state properties of ruthenium(II) polypyridyl complexes containing asymmetric triazole ligands

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this